Engineering Materials_Hand Notes
INTRODUCTION
The most common materials used for construction works
are-
Ø Stone
Ø Brick
Ø Cement
Ø Sand
Ø Concrete
Ø Timber
Ø Soil
Ø Ferrous & Non-Ferrous Metals
Ø Plastics
etc.
The necessity of knowledge
about construction materials
Ø To
have the idea of different types of materials
Ø To
have a preliminary knowledge about their preparation, types, properties and
uses
Ø To
know the suitability in different types of construction
STONE
Types of Stone
- Natural Stone
- Artificial Stone
Origin
Natural stone is obtained from rock.
Classification
of Rocks
1) Geological
classification
2) Physical
classification
3) Chemical
classification
4) Classification
based on hardness of the stone
Geological Classification
Ø Igneous Rocks
ü Granite
ü Basalt
Ø Sedimentary Rocks
ü Sandstone
ü Limestone
Ø Metamorphic Rocks
ü Marble
ü Quartzite
Physical
Classification
Ø Stratified Rocks
ü All Sedimentary Rocks
Ø Unstratified Rocks
ü All Igneous Rocks
Ø Foliated or Laminated Rocks
ü All Metamorphic Rocks
Chemical Classification
Ø Silicious Rocks
- • Predominant constituent is Silica
- • Very hard & durable
- • Not easily affected by weathering agents
- • Granite, Quartzite etc.
Ø Argillaceous or Clayey Rocks
- • Predominant constituent is clay
- • Hard, durable, dense & brittle
- • Laterite, Slate etc.
Ø Calcareous Rocks
- • Predominant constituent is Calcium Carbonate
- • Durability depends upon surrounding atmosphere
- • Limestone, Marble etc.
Classification Based upon Hardness of Stone
Ø Very Hard Rocks
- • Granite, Taconite etc.
Ø Hard Rocks
- • Basalt, Quartzite etc.
Ø Medium Rocks
- • Dolomite, Limestone etc.
Ø Soft Rocks
- • Gypsum, Sandstone etc.
Uses of Stone
Ø In
masonry work
Ø For
lintels and vertical columns
Ø For
covering floors of buildings
Ø For
paving of roads and foot paths
Ø For
the construction of roads in form of boulders and aggregates
Ø As
an aggregate in cement
Ø Base
material for water and sewage filters, in case of water works and sewage
treatment plants
Ø For the manufacture of cement and lime
Ø Stone may be used to give massive and pleasing appearance to the building
Ø Stone is used as ballast in railway tracks
Characteristics and Qualities of Good Building
Stone
Ø The
stone should be easily and economically obtainable
Ø The
stone should be hard, strong and durable
Ø It
should be able to withstand the deteriorating action of rough weather
Ø It
should have fine-grained compact texture. The shade of the stone should be of
pleasing nature especially where it is to be used in face work
Ø It
should be capable to withstand the effects of smoke and acidic atmosphere. This
is particularly important for the stones to be used in very industrialized
cities, having polluted atmosphere
Ø The
stone should be free from soft patches, flaws, cavities and cracks
Ø The
stone should be capable to withstand the effects of ordinary fires, without
suffering any serious damage
Ø It
should be easily workable
Ø It
should not absorb more than 5 % moisture of its weight when kept immersed in
water for 24 hours
Ø Specific
Gravity of stone should not be less than 25
Ø The
fracture of the stone should be sharp, even and clear
Decay or Deterioration of Stones
The causes are -
Ø Temperature
variation
Ø Wetting
and drying of stones
Ø Frost
action
Ø Polluted
atmosphere
Ø Living
organisms
Ø Vegetation
Ø Rain
water
Ø Wind
Ø Chemical
disintegration
Artificial Stone
Artificial or cast stone is
hardened plain cement concrete, moulded in suitable shape and size.
Preparation
Ø Artificial
stones consist of 1.5 parts of coarse aggregate of size 3 mm to 6 mm and
1.5 parts of fine aggregate of size less than 3 mm.
Ø Both
coarse aggregate and fine aggregate are obtained from natural stones.
Ø Both
the aggregates are mixed and this mass forms three parts.
Ø One
part of cement is added to three parts of mix of coarse aggregate and fine
aggregate and they are mixed dry
Ø If
any specific color effect is to be developed in the cast stone, suitable
pigment is added to the dry mix
Ø Lastly
water is added to the dry mix to obtain a mixture of workable consistency
Ø The
plastic mix is then pressed into moulds, cured and dried
Advantages
Ø They
can be cast in any shape and size
Ø They
can be made stronger than natural stone
Ø They
can be easily moulded and seasoned at the site of work
Ø Holes
may be kept during casting which may be required for pipe or electric wire
fittings
Ø Their
mass is more homogeneous and thus their properties are more reliable
Ø They
can be designed for any strength
Ø They
normally do not have any defect
Ø They
are more durable than natural stone
Ø They
do not require any transportation as they can be cast at site
Ø The
progress of work will be faster with precast stones
Stone Quarrying
The site from where stones are
excavated is known as simply quarry or quarry site. The process of taking out
stones from quarry is known as quarrying of stone.
Selection of
Quarry Site
Ø Distance
of quarry from road, railways etc. should not be very large
Ø Sufficient
amount of stone should be assured from the site
Ø Availability
of equipment, labor etc. also affect the selection of site
Ø Quality
of stone available from the quarry should be good
Ø Drainage
from quarry should be easy
Ø Adequate
facilities for transportation of stone should be available
Ø The
site should be away from built up areas when blasting is required
BRICKS
It is a regular sized
rectangular unit, used for most of the building works. It is used as substitute
for stone, where stone is not available.
Ingredients of Good Brick Earth
A good brick earth mainly consists of silica (sand)
and alumina (clay).
Ingredients of Good Brick Earth
Ø Alumina
(Clay)
Ø Silica
(Sand)
Ø Lime
Ø Oxide
of Iron
Ø Magnesia
They are mixed in such a proportion that the resulting
mass with water is a plastic mass that could be easily moulded and dried
without undergoing shrinkage, cracking or warping.
Alumina
(Clay)
v Alumina
is the chief constituent of every kind of clay
v A
good brick earth should contain between 20 to 30 % of alumina
v Alumina
provides plasticity to earth, so that it can be moulded
If bricks contain excess amount of alumina and
insufficient sand they shrink, crack and warp on drying and burning
Silica
(Sand)
v The
percentage of silica in a good brick earth should lie between 50 to 60 %
v Presence
of silica prevents cracking, shrinking and warping of raw bricks
v Excess
amount of silica destroys the cohesion between particles and makes the bricks
brittle and weak
v Hence,
durability of the bricks depends largely on the proper proportion of silica & alumina in brick earth
Lime
v Small
quantity of lime in brick earth is desirable
v Slight
amount of lime in a very finely powdered form acts as a flux and causes silica
to fuse slightly at kiln temperature
v Such
slightly fused sand acts as a very hard cementing material and bricks of large
strength and durability are obtained
v Lime
present in small proportion also prevents shrinkage of raw bricks
v Excess
amount of lime causes the brick to melt and its shape is lost
v If
lumps of lime are present, they are converted in to quick lime after burning
v The
formed quick lime slakes and expands due to moisture and causes splitting of
bricks into pieces
Oxide of
Iron
v Small
quantity of oxide of iron (about 5 to 6 %) is desirable in good brick earth
v It
also helps silica to fuse at comperatively low temperature like lime
v The
color of bricks depends on the proportion of iron oxide present in the brick
earth
v The
bricks having very small amount of iron oxide are yellow in color
v Too
much iron oxide makes the bricks dark, blue or blackish
v Iron
also increases the durability and impermeability of the bricks
Magnesia
v A
small proportion of it decreases the shrinkage and gives yellow tint to the
bricks
v Excess amount of magnesia causes bricks to decay
Proportion of the Ingredients of Typical Good
Brick Earth
Ingredients |
Alumina
|
Silica
|
Lime & Magnesia |
Iron
Oxide |
Organic Matter |
Percentage |
20-30
% |
50-60
% |
6-10
% |
4-8% |
3-6 %
|
Harmful Ingredients of Brick Earth
Harmful Ingredients of Brick Earth |
•
Lime |
Lime
v Presence
of lime in large amount is harmful
v Calcium
Carbonate present in lumps is converted to quick lime (CaO) after burning of
bricks
v When
these bricks come into contact with moisture, quick lime slakes and causes
disruption of bricks because of its expansion
v Excess
amount of lime also causes the brick to melt and its shape is lost
Pebbles of
Stone and Gravel
v They
do not allow thorough mixing of the erth and the bricks containing pebbles and
gravels are considered very week
v Such
bricks cannot be broken at the desired section and they break very irregularly
Iron Pyrites
Presence of iron pyrites causes
crystallization and disintegration of bricks during burning
v It
causes discoloration of bricks in the form of black slag
Alkalies
v The
alkalies are mainly salts of sodium and potassium
v Alkalies
act as flux in the kiln and cause fusion, warping and twisting of the bricks v Alkalies present in bricks absorb
moisture from the atmosphere
v Such
bricks when used for masonry work cause deposition of white powder on the
surface. Because when drying; the salts, which have come to the surface with
moisture, get deposited
v This
action is known as efflorescence, which seriously spoils the appearance of the
building Organic
Matter
v Presence
of organic matter and vegetation in the brick earth render the bricks porous
Presence of
Reh or Kallar
v These
consists of sodium chloride, sodium carbonate and sodium sulphate
v These
elements re-crystalize after burning of bricks and deposit on the surface of
masonry in form of whitish spots
v This
causes pealing off the plaster and bricks and ultimately leads to the failure
of structure
Broad Classification of Bricks
Classification of Bricks
ü
First
Class Bricks
ü
Second
Class Bricks
ü
Third
Class Bricks
ü
Over
Burnt or Jhama Bricks
ü
Under
Burnt or Pilla bricks
First Class
Bricks (S-grade, BDS 208:2002)
Properties
v Size
of the burnt brick is exactly 9.5” x 4.5” x 3”
v The
brick earth is free from small pebbles, lime lumps, organic matter and sodium
salts
v Well
burnt
v Color
is uniform yellow or red
v Surface
is regular and sides are parallel, edges are sharp and at right angles to each
other
v Have
firm, compact and uniform texture
v No
sign of efflorescence
v Crushing
strength more than 280 kg/cm2 (mean value) and 245 kg/cm2
(individual minimum value)
v Surface
is so hard that finger nails are not able to make any impression on its surface
v Does
not absorb water more than 10 % of its own dry weight after immersion of 24
hours in cold water
v Metallic
ringing sound emits when two bricks are struck against each other
v Does
not break when it is dropped on a hard ground from a height of 1 meter
Uses
v Used
in all works of long durability, say 100 years
v Used
for buildings that expose to corrosive environment
v Used
as coarse aggregate of concrete
Second Class
Bricks (A-grade, BDS 208:2002)
Properties
v Well
burnt or slightly over burnt
v Color
is uniform yellow or red
v Generally
regular and uniform shape, size and color
v Uniform
texture
v No
appreciable sign of efflorescence
v Ringing
sound emits when two bricks are struck against each other
v Does
not absorb water more than 15 % of its own dry weight after immersion of 24
hours in cold water
v Crushing
strength more than 175 kg/cm2 (mean value) and 154 kg/cm2
(individual minimum value)
v No finger nail impression
Uses
Used in less important structures
v Used
for general purposes
Third Class
Bricks (B-grade, BDS 208:2002)
Properties
v Generally
under burnt
v Soft
and light red colored
v Size
and shape are not regular
v Intensive
efflorescence
v Texture
is not uniform
v Emit
a dull sound when struck against each other
v Does
not absorb water more than 20 % of its own dry weight after immersion of 24
hours in cold water
v Crushing
strength more than 140 kg/cm2 (mean value) and 105 kg/cm2
(individual minimum value)
v Leave
finger nail impression
Uses
v Not
used for important and permanent works
v Mostly
used for temporary works
Over Burnt
or Jhama Bricks
v Over
burnt
v Shape
vitrified and distorted
Uses
v Can
not be used in construction works
v Used
for making aggregate for lime concrete for foundation v As a road material
Under Burnt
or Pilla Bricks
v Half
burnt
v Yellow
color
v Low
strength
Uses
v Crushed
to powder form and used as surkhi
Manufacture of Bricks
- ü Preparation of Clay
- ü Pugging or Tempering of the Clay
- ü Moulding of Bricks
- ü Drying of Bricks
- ü Burning of Bricks
Preparation
of Clay or Earth
v Preparation
of clay involves operations like removing the top loose earth, then digging,
cleaning, weathering and blending of the earth
v After
removing the top unsuitable soil, the clay is dug either by manual labor or by
power excavators
v Dug
out clay is spread on the leveled ground and all the pebbles, gravel, kankar,
vegetable matter etc. are removed from the clay
v The
clay is left exposed to atmosphere for softening, known as weathering of clay
v Digging
the earth before rains is advantageous as full monsoon can be utilized for
weathering
v After
weathering, the earth is chemically analyzed and if there is any deficiency of
any ingredient, it is mixed with the earth
v Now
preparation of clay is completed
Pugging or
Tempering of Clay
v Tempering
or pugging of clay involves breaking up of the prepared clay, watering and
kneading till the earth becomes a homogeneous mass
v Water
is added to clay in required quantity and the whole mass is kneaded under the
feet of men or cattle
v
Where good bricks are required to be
manufactured on a large scale, tempering of clay is usually done by pug-mill
Moulding of
Bricks
After tempering of clay, bricks
should be moulded as soon as possible; otherwise pugged clay may become stiff
and moulding of bricks may become difficult
v The
bricks can be moulded by
ü Hand
moulding
ü Machine
moulding
v Moulds
are rectangular boxes without any top and bottom. They may be made of steel or
timber
Drying of
Bricks
Wet bricks have to be dried
before they are fed for burning in the kilns. The objectives of drying the
bricks are
v To
remove as much of moisture from the bricks as possible, so as to save time and
fuel during the burning
v To
avoid the chances of cracking and distortion of bricks during the burning
v To
increase the mechanical strength of the bricks, so that they can be handled and
stocked without any damage to the bricks
Burning of
Bricks
v Burning
of bricks is a very important operation in the manufacture of bricks
v It
imparts strength and hardness to the bricks and makes them dense and durable
v When
temperature of bricks reaches at 650° C, while burning, water of
crystallization is removed
v At
about 1100° C, the two main constituents of brick, silica and alumina, combine
with each other and bricks become dense and strong
v Bricks
are burnt either in clamps or in kilns
Kilns
The kiln is a system, designed
more scientifically, to burn the bricks in very large numbers. Two types of
kilns are generally used
v Intermittent
kiln
v Continuous
kiln
Intermittent
Kiln
v Operation
of burning the bricks is not continuous
v The
kiln is loaded, then fired, then allowed to cool and lastly unloaded v This completes one cycle of
operations
Disadvantages
v Supply
of bricks is intermittent
Quality of burnt bricks is not
uniform. Bricks near bottom are over burnt and those near top are under burnt
v There
is wastage of fuel as kiln is to be cooled down every time after burning
Continuous
Kiln
v Continuous
in operation and ensures continuous supply of burnt bricks
v All
operations like loading, firing, cooling and unloading are carried out
simultaneously in these kilns
v Mostly
used Continuous Kilns are
ü Bull’s
Trench Kiln
ü Hoffman’s
Kiln
ü Tunnel
Kiln
Hoffman’s Kiln
v This
kiln is circular in plan
v The
chimney is placed at the centre and twelve chambers are arranged around the
chimney forming a circular ring
v Each
chamber has a door in the external wall which is used for loading and unloading
of bricks
v All
the chambers have communicating doors in the walls separating each other and
all the chambers have a connection with chimney with radial flues
v The
kiln has permanent roof but fuel holes are provided to drop the fuel in the
kiln from top
v In
this kiln, all the chambers are subjected to loading, drying and pre-heating,
burning, cooling and unloading operations successively and all these operations
remain going on all the time simultaneously
All the twelve chambers of the kiln may be functioning as follows
Chamber
no. |
Operation involved |
1 |
Loading |
2, 3, 4, 5 |
Drying & Pre-heating |
6, 7 |
Burning |
8, 9, 10, 11 |
Cooling |
12 |
Unloading |
The circulation of flue gas with this arrangement
Cool air enters the kiln through open doors of
chambers 1 and 12
v Now
this heated air or gas enter the burning chambers 7 and 6, where it performs
the burning of bricks. Fuel is dropped in these chambers from the top
v After
performing burning of bricks, hot gas is led to chambers 5, 4, 3 and 2 where
they perform drying and pre-heating of freshly loaded bricks
v The
communicating door of chamber 2 is closed and cooled gas is led to chimney
through the radial flue of this chamber
v Care
should be taken that all radial flues except of chamber 2 remain closed and all
communicating doors except in the wall between chambers 1 and 2 remain open for
this particular arrangement. Outer loading and unloading doors remain closed
except for the two chambers, which are being loaded and unloaded
After the burning of bricks of chamber 7 and 6, the
pattern of circulation will be as follows
Chamber
no. |
Operation involved |
12 |
Loading |
1, 2, 3, 4 |
Drying & Pre-heating |
5, 6 |
Burning |
7, 8, 9, 10 |
Cooling |
11 |
Unloading |
Advantages of Hoffman’s Kiln
v There is perfect control on the heat
v Supply of bricks is continuous and regular
v Pre-heating of the bricks by hot gases before they escape into the atmosphere, considerably reduce the consumption of the fuel
v Bricks are burnt evenly and thus bricks of good quality are produced
v Percentage of first class bricks is the highest
Disadvantages of Hoffman’s Kiln
v Initial cost of construction is high
v This kiln requires regular demand of the bricks which may not be possible
Desirable Characteristics of Good Bricks
v The color of good brick should be uniform. It may be deep red or yellow
v Bricks should be uniform in shape with all its edges sharp, straight and at right angles to each other
v Size of the bricks should be standard (24cm x 11.5cm x 7cm) as prescribed by Bangladesh Standards (BDS, 2002)
v The bricks should have fine, dense, compact and uniform texture.
v First class bricks should not absorb water more than 10 % of its own dry weight after immersion of 24 hours in cold water
v Crushing strength more than 280 kg/cm2 (mean value) and 245 kg/cm2 (individual minimum value) (BDS, 2002)
v The bricks should be so hard that finger nails should not be able to make any impression on its surface when scratched
v Two bricks when struck against each other should emit ringing sound
v Bricks should be soundproof and also of low thermal conductivity
v Bricks should not break when dropped flat on a hard ground from a height of 1 meter
Tests for Bricks
v Absorption
of Water Test
v Crushing
Strength Test
v Hardness
Test
v Shape
and Size Test
v Soundness
Test
v Test for Presence of Soluble Salts
Coloring of Bricks
v The
color of the bricks depends upon the following factors
ü Burning
temperature of bricks
ü Type
of fuel used during burning
ü Chemical
composition of the brick earth
ü Nature
of sand used during moulding
ü Degree
of dryness achieved before burning
ü Amount
of air admitted to the kiln during burning
v The
color attained by any of the above causes is known as the natural color of the
brick
v Bricks
can be colored artificially also
ü By
dipping (immersing in coloring mixture)
ü By mixing appropriate coloring material during preparation of brick earth/clay
Fire Bricks or Refractory Bricks
v These bricks are manufactured from specially designed earth, so that after burning, they can withstand very high temperatures without affecting its shape, size and strength
v They are used for lining of chimneys, furnaces etc., where usual temperatures are expected to be very high
CEMENT
v Cement
is a very important building material, which is extensively used in the
construction industry
v Cement
is always used in the form of mortar and concrete in construction works and
never alone
Natural Cement
v Natural
cement is manufactured by burning and then crushing the natural cement stones
v Natural
cement stones are such stones which contain 20 to 40 % of argillaceous matter
and remaining content mainly calcareous matter
Argillaceous Matter |
Calcareous Matter |
Silica, Alumina & Iron Oxide (SiO2, Al2O3,
Fe2O3) |
Compounds of Calcium
& Magnesium (CaCO3, MgCO3) |
v Since
chemical composition of natural cement stones vary considerably from place to
place, the properties of natural cement also vary
v Even
cement being manufactured in one factory may be varying in properties
v For
example, hydraulic properties of cement are entirely dependent on the
percentage of clayey materials present. If
% of clay is high, quick setting cement is produced with low ultimate
strength
v Examples: Roman cement, Pozzolana cement
and Medina cement
Artificial Cement
v Artificial
cement is manufactured by burning appropriately proportioned mixture of
calcareous and argillaceous matters at a very high temperature and then
grinding the resulting burnt mixture to a fine powder
v The
burnt mixture of calcareous and argillaceous matters is known as clinker
v A
little percentage of gypsum is also added in the clinkers before grinding them
to fine powder
v Gypsum
is added to delay the setting action of the cement for some time so that, it
can be properly mixed, applied and finished
v The
setting time can be varied by suitably varying the percentage of gypsum
Advantages
of Artificial Cements
v Can be manufactured in any desired color
v Initial setting time can be easily regulated
v Rate
of hardening can be regulated
v Rate
of evolution of heat can be regulated
v Properties
can be maintained always same by maintaining same composition of raw material
v Can
be manufactured in very large quantities
Ordinary Portland Cement
v Common
variety of artificial cement is known as normal setting cement or ordinary
cement
v This
cement was first invented by Joseph Aspdin of England in 1824
v This cement resembles very closely to a sandstone, which is found in large amount at a place Portland in England and thus this cement is also referred to as Portland cement
Composition of Ordinary Portland Cement
Name of Ingredients |
Typical Percentage (%) |
Average Percentage (%) |
Alumina or Clay (Al2O3)
|
3-8 |
5.0 |
Silica (SiO2) |
20-25 |
62.2 |
Lime (CaO) |
60-70 |
22.0 |
Iron Oxide |
2-4 |
1.5 |
Magnesia (MgO) |
1-4 |
3.0 |
Sulphur Trioxide |
1-5 |
1.4 |
Alkalies (Soda &
Potash) |
0.2-1 |
1.0 |
Calcium Sulphate/Gypsum |
3-5 |
4.0 |
Functions of Ingredients of Cement
Alumina or
Clay
v Alumina
is responsible for setting action of cement
v Larger
the amount of alumina present in the cement, quicker it will start setting
v Excess
quantity of alumina weakens the cement
v Alumina forms complex aluminates with silica and calcium and imparts the setting property to the cement
Silica
v It
also goes in to chemical combination with calcium and forms hard silicates
which are responsible for imparting strength to the cement
Lime
v It
is the most important ingredient of the cement and its amount in cement is
above 60 % of the total contents
v Its
proportion should be carefully decided
v If
lime is added in excess quantity, some part of it is left in forms of free lime
which causes expansion and disintegration of cement at the time of setting and
hardening
v Lesser
than the required quantity will cause decrease in the strength of the cement,
as then sufficient calcium silicates will not be formed, which are mainly
responsible for the strength characteristics of the cement
Iron Oxide
v Iron
oxide mainly imparts color to the cement
v Besides
this, it also goes into chemical combination and helps to increase strength and
hardness of cement
Magnesium
Oxide
v It
also imparts strength and hardness to cement, but only when present in small
amount
Sulphur
Trioxide
v Small
percentage of sulphur renders cement sound
v Excess
amount of it may make it unsound
Alkalies
v Alkalies,
present in the raw materials used for the manufacture of cement are mostly
drive out by the flue gases during burning
v Still
it may be present in the cement in very small amount
v Excess
amount of alkalies cause efflorescence in the cement
Calcium
Sulphate/Gypsum
v Gypsum
is used to retard or prolong the initial setting action of the cement
Harmful Constituents of Cement
Alkalies
v Alkalies
are oxides of potassium and sodium
v If
amount of alkalies exceeds 1 % it causes unsoundness of cement
Magnesium
Oxide
v If
amount of MgO exceeds 5 % it causes cracks in hardened mortar or concrete as it
burns at about 1500° C and slakes very slowly when mixed with water
Proportioning of Cement Ingredients
Acidic Constituents
Ø SiO2, Al2O3, Fe2O3
Ø Argillaceous Materials
Alkaline Constituents
Ø CaO & MgO
Ø Calcareous Materials
Neglecting the rest (i.e., CaSO4 & other
compounds ≈ 8% of total mass), the % of acidic and alkaline constituents are 32
and 63.5 respectively. The ratio of these constituents is given by:
Sometimes, the index of cementation value (or cement moduli) is used for proportioning raw materials of cement, which is given by:
In the above index, % molecular weight of the individual ingredients is used. Thus,
v Either index can be used for proper proportioning of cement constituents
v It is clearly understandable that, the calcareous and argillaceous materials should be carefully selected and proportioned
v On the other hand, Clinkering helps in a through and intimate mixing of raw materials
v It ensures a thorough and complete chemical reaction between the ingredients to form the following mineral constituents:
Name of Compound |
Oxide Composition |
Abbreviation |
Range of Percent Composition |
Tri-Calcium Silicate |
3 CaO.SiO2 |
C3S |
45-55 |
Di-Calcium Silicate |
2 CaO.SiO2 |
C2S |
20-30 |
Tri-Calcium Aluminate |
3 CaO.Al2O3 |
C3A |
9-13 |
Tetra-Calcium
Aluminoferrite |
4 CaO.Al2O3.Fe2O3
|
C4AF |
8-20 |
Calcium Sulphate (Gypsum) |
CaSO4 |
---- |
2-6 |
Other Compounds |
---- |
---- |
2-8 |
Functions/Hydration of Mineral Constituents
v All
the cement constituents are in dry state
v As
soon as water is added to cement, chemical reactions start simultaneously
between them
v The
term hydration is applied to all reactions of cement with water
v The
process of hydration is essentially the formation of minute crystals of calcium
and gels from the solution of cement and water. It continues for a long time.
The hydration rate of different mineral compounds is different as mentioned
below
v As
the crystals adhere to one another and to the surface of sand or inert
particles of aggregate (with which cement is mixed), the entire mixture gets
set and hardened resulting in gaining strength
v The
strength developed depends on the amount of gel formed and the degree of
crystallization
v After
setting is initiated, hardening of cement follows and in the course of time,
hydration process advances further into the interior
Tri-Calcium
Aluminate (C3A)
v C3A
is one of the first compounds to start hydrating after addition of water
v Hydration
leads to immediate stiffening of the paste, known as flash setting
v The
hydration completes in a day
v It
is responsible for early setting of cement and hampers the workability
v Gypsum
is added to retard the setting action
v C3A
does not contribute any strength to concrete and only contributes to the
setting action of cement
Trii-Calcium
Silicate (C3S)
v Hydration
of C3S starts after that of C3A
v Its
hydration is responsible for the initial strength of cement
v The
strength acquired during first 7 days is mostly due to hydration of C3S
Di-Calcium
Silicate (C2S)
v C2S
reacts with water at a very slow rate
v Hydration
of C2S continues for several weeks
v It
is responsible for the progressive strength of cement, especially strength
gaining after a week of mixing
Tetra-Calcium
Aluminoferrite (C4AF)
v It reacts with water instantly after mixing and hydrates simultaneously with C3A
v C4AF has no influence on setting action of cement and hardening
Heat of Hydration
v The
setting action of cement is a process of hydration and is accompanied by
generation of heat called ‘Heat of hydration’
v The
C3A generates much of the heat. Similarly, C3S also
generates considerable heat during hydration
v The
process of heat generation is quite rapid in the initial phase of the setting,
but its rate diminishes with the passage of time
v 1
gram of OPC generates about 120 calories on setting, out of which, 80 calories
are generated in first 7 days
v Special
care has to be taken to dissipate this heat, otherwise mass concrete works
(dams, rafts etc.) are likely to develop cracks resulting in weakening the
concrete
v A
rise in temperature to the extent of 15° to 25°C is observed in many cases. The
rise in temperature is the largest during the first few days. But in the large
masses of concrete, the maximum temperature is generally reached as late as
after 2 to 3 months
v Therefore, in such cases, the devices for cooling down the interior have to be adopted
False Setting of Cement
v False
setting is the name given to the abnormal premature stiffening of cement within
a few minutes of mixing with water
v It
differs from flash setting by following
ü No
appreciable heat is evolved in this case
ü Re-mixing
the cement paste without further addition of water restores plasticity of the
paste
ü The
restoration will not cause strength loss as long as it does not set in the
normal manner
Some Causes
of False Setting
v Dehydration
of gypsum while grinding to powder with too hot clinker
v Semi-hydrate
(CaSO4.½H2O) or anhydrite (CaSO4) are formed
and if cement is mixed with water, this CaSO4 hydrates to form
gypsum again (CaSO4.2H2O). thus setting takes place with
resulting stiffening of the paste
v Excess
alkalies present in cement may cause false setting. During storage, the
carbonates of alkalies reacts with Ca(OH)2 liberated by hydrolysis
of C3S to form CaCO3. This precipitates and induces a
rigidity of the paste
Manufacturing of Cement
Considerations
for the Location of Factory Site
v Climatic
conditions at site should be favorable for the manufacture of cement
v Required
labor should be available abundantly and economically
v Local
and nearby area should provide adequate market for sale
v Supply
of electricity should be available abundantly, economically and continuously
v Raw
materials should be available locally
v Transportation
facilities should be available adequately
v Gardens,
parks etc. and other recreation centers should be available
Process of
Manufacturing
Cement can be manufactured by following two methods-
1) Dry
process (Modern technology)
2) Wet
process (Old technology)
The following three distinct operations have to be
performed in manufacturing of cement by either dry process or wet process.
1) Mixing
of raw materials
2) Burning
3) Grinding
Cement Storage
Cement Silos
v In
factory, cement is stored in a large sized, reinforced concrete vertical
cylinder, called silos
v Their
diameter varies from 7m to 10m and height from 15m to 24m
v Cement
is drawn from them at the bottom
Cement
Packing
v Cement
is packed in gunny bags or in bags of cloth or paper
v Packing
is done with the aid of automatic weighing and packing machines
v A
special rotary type screw feeding device armed with a trigger is provided for
filling the bags
v When
a specific quantity of cement is admitted in each bag, the trigger is operated
by the weight of the filled bag and the feed is automatically closed
v OPC
weighs 50 kg per bag, which is equivalent to 1.25 cft in volume
Cement
Storage by User
The precautions for the storage of cement during
works
v Cement
should be stored in a dry place and on a raised platform, which is covered and
guarded from sun, wind and rain. A maximum of 15 bags is placed vertically
v Long
periods of storage should be avoided as far as possible
v Storage
of cement in rainy season is not recommended
Types of Portland Cement
No. |
English Description (BS) |
American Description (ASTM) |
1 |
Ordinary Portland |
Type I |
2 |
Modified Portland i. Air
Entraining ii. Expanding
|
Type II |
3 |
Rapid Hardening Portland |
Type III |
4 |
Quick Setting Portland |
---- |
5 |
Low Heat Portland |
Type IV |
6 |
Sulphate Resisting Portland
|
Type V |
7 |
Blast Furnace |
Type IS |
8 |
Pozzolana Portland |
Type IP |
9 |
White Portland |
---- |
Air
Entraining Cement
v 0.01
to 0.05 % by weight air entraining foaming agents are used. Agents are resinous
materials such as vinsol, resin, darex etc. They are added during the grinding
of clinker
v Concrete
made with such cement contains minute, well-distributed air bubbles throughout
the mass. Air bubble reduces strength by 10 to 15 % and hence, the bubbles
should not be more than 3 to 4 % of the volume of concrete
v Air
entrainment improves the workability and durability of cement
v Such
cement is resistant to severe frost action, fire, surface scaling and other
similar effects
Rapid
Hardening Cement
v This type of cement can be
produced by
i) Increasing the fineness of cement
(i.e., by increasing their specific surface) ii) Allowing
a low percentage of alumina since Al2O3 sets early and
offers a covering layer over Calcium and Silica compounds and retards their
hydration and hence hardening
iii) Increasing
the C3S content to impart rapid hardening. This requires an increase
in lime contents and the consequent careful clinkering at a higher temperature.
With the increase in lime content in raw materials, however, there is always a
danger of the presence of free lime in cement
v Used
for highway slabs, which is to be open to the traffic at the earliest possible
moment
v Used
in cold weather concreting because its rapid hardening and high rate of heat
evolution protects concrete against freezing
v Also
used for manufacturing of precast elements
Quick
Setting Cement
v Cement
possessing initial setting time of 5 minutes and final setting time of 30
minutes
v It
is difficult to work with this cement, as little time is allowed for mixing and
laying of concrete; i.e., these works have to be completed in 5 minutes
v Quick
setting property is achieved by
i) Increasing fineness ii) Adding small percentage of Al2(SO4)3
iii) Adding
very little or no percentage of gypsum to the clinker during grinding
v Al2(SO4)3
together with Al2O3 (as an ingredient of cement) hydrates
quickly to form C3A and C4AF more in quantity than OPC
v Used
for concreting under running water as quick setting action prevents cementing
material from being washed out by running water
Low Heat
Cement
v In
mass concrete structures such as dams, retaining walls, bridge abutment, raft
etc., the rate of dissipation of heat due to hydration from the surface is much
lower than that generated
v It
causes rise in temperature inside the concrete mass and may develop thermal and
shrinkage cracks if proper precautions for dissipating the thermal gradient are
not taken
v Under
this circumstance, the low heat cement can be effectively used
v Cement
ingredients are proportioned in such a way that C3A and C2S
are formed in less amount, but C2S is formed in increased amount so
that C2S and C3S collectively impart the same strength as
OPC
v The
rate of heat generation is slow initially (as the hydration rate is slow), so
both setting and hardening rates are slow initially. But in the later stage
both rates are faster than the OPC
Typical composition of
Low Heat Cement
Type |
C3S (%) |
C2S (%) |
C3A (%) |
C4AF (%) |
OPC |
48 |
24 |
10 |
9 |
LHC |
24 |
48 |
5 |
14 |
Pozzolana
Cement
v Pozzolanic
materials are mainly burnt clay like surkhi, fly ash or shale. They can be
added to cement to react with free lime present in OPC. These materials, though
inert, are capable of combining with lime when wet and form cementitious
products. Volcanic ash is also used as pozzolana
v These
materials are pulverized and then mixed with cement. Or, they can be mixed with
clinker and ground with it
v The
percentage usually varies from 10 to 25 % by weight of the finished cement
v Pozzolana
cements impart plasticity and workability to mortars and cement
v The
free lime present in OPC is liable to leaching action by percolating waters in
dams and other hydraulic structures, which are thereby rendered permeable.
v Pozzolanic
cements, on the other hand, will impart impermeability to hydraulic structures
v An
excess of pozzolanic materials makes mortars and concrete shrink more. Their
strength also is proportionately reduced
Tests of Cement
- Fineness Test
- Consistency Test
- Test for Strength
• Compressive
Test for Setting Time
• Initial Setting
• Final Setting
Test for Soundness/Expansion Test
Test for Chemical Composition
SAND
v Sand
is a form of silica of small grains
v Formed
by decomposition of sandstone due to various weathering effects v Mostly obtained from pits,
shores, river beds and sea beds
Sources of Sand
Pit Sand
v Obtained
by forming pits into the soil
v It
is sharp, angular, porous and free from harmful salts
v Clay
and other impurities should be washed and screened before using in engineering
purposes
v Fine
pit sand, when rubbed between fingers, should not leave any stain on it. It
indicates the presence of clay
v Used
for the mortars
River Sand
v Found
at river beds and banks
v Fine,
round and polished due to rubbing action of water currents
v Having
less frictional strength because of roundness
v Almost
white in color
v Grains
are smaller than pit sand, and hence more suitable for plastering work
v Normally
available in pure condition and hence can be used for all kinds of civil engineering
works
Sea-Sand
v Obtained
from sea-shores
v Fine,
rounded and polished due to rubbing action of water
v Light
brown in color
v Worst
of the three kinds of sand because of containing lot of salts
v Salts
absorb moisture from atmosphere and cause permanent dampness and efflorescence
in the structure
v Sea
salts also retards the setting action of cement
v Besides,
it contains shells and organic matter which decompose in the body of mortar and
concrete and hence reduce their life and strength
v Sea
sand should be discarded as far as possible
Desirable Properties of Sand
v Inert
completely (i.e. should not have any chemical activity)
v Grains
should be sharp, strong and angular
v Should
not contain hygroscopic salt
v Should
not contain clay & silt, which are harmful ingredients (usually 3-4 % clay
& silt is ordinarily permitted for practical
reasons)
v Should
not contain any organic matter
Functions of Sand in Mortar/Concrete
v Offers
requisite surface area for the film of finding material to adhere and spread
v Increases
the volume of mortar and consequently makes mortar more economical
v A
well-graded sand adds to the density of mortars and concrete
v Prevents
excessive shrinkage of mortar
v Since
inert material, it renders structure more resistant against atmospheric actions
Classification of Sand
v Classification
is based on ASTM Standards
Fine Sand
ü FM = 2.20~2.60
Medium Sand
ü FM = 2.60~2.90
Coarse Sand
ü FM = 2.90~3.20
Fineness Modulus (FM) of Sand
Example of FM of Sand
Sieve No |
Sieve size (mm)
|
Wt. of can (gm)
|
Wt.
of Can+
sand (gm) |
Wt. Retained (gm)
|
% Retained |
Cum.
% Retained
|
% Finer |
1.5 in |
|
70 |
70 |
0 |
0 |
0 |
100 |
3/4 in |
|
70 |
70 |
0 |
0 |
0 |
100 |
3/8 in |
|
70 |
70 |
0 |
0 |
0 |
100 |
No. 4 |
4.76 |
70 |
70 |
0 |
0 |
0 |
100 |
No. 8 |
2.38 |
70 |
70 |
0 |
0 |
0 |
100 |
No. 16 |
1.19 |
70 |
75 |
5 |
2.5 |
2.5 |
97.5 |
No. 30 |
0.595 |
70 |
130 |
60 |
30 |
32.5 |
67.5 |
No. 50 |
0.297 |
70 |
200 |
130 |
65 |
97.5 |
2.5 |
No. 100 |
0.149 |
70 |
75 |
5 |
2.5 |
100 |
0 |
|
|
|
|
|
|
|
|
|
|
|
SUM= |
200 |
100 |
|
|
Tests for Sand
Tests for
Presence of Silt and Clay
1) If
silt & clay are present in sand, then could be found out by determining the
percentage loss in weight of a sample of sand after washing the same with the
aid of clean water.
2) However,
field test can be performed by rubbing a small amount of sand between finger
tips. If clay spots are left on finger tips, it indicates the existence of clay
in the considerable amount.
Test for
Presence of Salt
v Can
be tested by putting some amount in mouth. The test will reflect the presence
of any salt.
Test for
Organic Matter
v Make
3 % solution of NaOH & put some sand into the solution.
v Close
the bottle for 24 hours and meanwhile shake the solution vigorously.
v The
color of the liquid turns brown if any organic matter is present in sand.
v The
darkness of color gives the estimation of the amount of organic matter exists
in the salt.
Substitute for Sand
If good sand is not available in the nearby of the
site, the substitutes may be used
Stone
Screenings
v Fine
particles obtained by screening crushed stones
v The
grains are sharp and strong and impart better strength to the concrete if used
Surkhi
v Obtained
from finely powered burnt clay (brick)
v Also
obtained by grinding slightly underburnt bricks
v It
distinguishes under the action of air and humididty
v Not
used for external mortar
Bulking of Sand
v Bulking
of sand means increase in volume. Fine aggregates (i.e. sand) increase in
volume when they posses some moisture
v It
is due to the formation of a thin film of water around the aggregate or sand
particles
v The
thickness of this film goes on increasing with more and more moisture. Therefore,
the increase in volume of sand mass continues. This increase in volume varies
20~30 % (volume basis) depending upon the fineness of sand. The finer will
undergo with greater increase in volume
v After
certain % of water (5~8 %, also depends on the fineness of sand), the volume of
sand starts decreasing with the further increase in water and eventually the
increased volume completely vanishes, and at this moment, the volume occupied
by sand becomes equal to the volume of dry sand
Importance
Bulking of sand effects water cement (w/c) ratio and
the proportioning of aggregate
MORTAR
v Intimate mixtures having the consistency of a paste and
prepared by mixing a binding material (e.g., cement, lime, surkhi etc.) and
inert matter (e.g., sand, stone, screenings etc.) and water in various
proportions
Types of Mortar
Cement
Mortar
v Consists
of mixture of cement, sand & water in suitable proportion
v Stronger
than any other mortar
v Commonly
used in the construction of load bearing wall, columns etc.
v The
proportion of cement to sand (volume basis) varies from 1:2 to 1:6 or even
more, such as
• Masonry
wall 1:6
to 1:8
• Foundation
concrete 1:3 to 1:4
|
RCC
works |
1:3 |
|
Arch
works |
1:3 |
|
Pointing
|
1:2 to 1:3 |
|
Plaster work |
1:3
to 1:4 |
Lime Mortar
v Mixture
of lime (fat, normal or hydraulic lime), sand & water
v If
fat lime is used, it should be slaked before using
v Fat
lime mortar proportion 1:1
v Ordinary
lime mortar proportion 1:2 v Hydraulic lime mortar proportion 1:4
v Hydraulic
lime has greater cementing power than others
Mud Mortar
v Mixture
of puddle mud and water at the required consistency
Gauged
Mortar
v Lime
mortar with having some cement to increase cementing properties
v Usually
used with fat lime mortar, as this kind of lime possesses very weak cementing
property
v Cement
in lime mortar increases its strength, hydraulicity and the rate of setting v Used for brick or stone masonry
in foundation
Preparation of Cement Mortar
v Sand
and cement are measured in a dry state and spread to a uniform thickness on a
non-porous platform. Cement is spread over sand. As usual, sand is measured in
ft3, but cement is measured by weight, 40 kg/ft3
v For
a given batch, the quantity of water to be added is calculated. One half of
that quantity is sprinkled on the above dry mix. The mixture is again turned
over twice or thrice to prepare a semi-wet mix
v The
remaining quantity of water is added to the semi-wet mix and again the whole
mixture is turned twice or thrice to form cement mortar of the required
consistency
v Now
the mortar is ready for use. All the work done in cement mortar should be kept
wet for about 15 to 21 days for curing by occasional sprinkling with water
Precautions in Using Mortar
v Bricks
or stones to be jointed by mortar should be used by soaking them in water for
at least 12 hours
v After
preparation of mortar, it should be used at its destined place as early as
possible; cement mortar within 30 minutes of adding water to it and lime mortar
within 36 hours
v Mortar
should be stiff but workable; i.e., it should be as stiff as possible without
affecting its convenience in use
v Works
made from mortar should be kept wet for two weeks to three
Tests for Mortar
Tensile
Strength Test
Using briquette apparatus with minimum cross-section
of 1.5”x1.5”
Compressive
Strength Test
By using cube (2”x2”x2”) made from cement mortar
Adhesive
Strength Test
v Arrange
two bricks in T-shape and use mortar at the intersection line.
v When
they gain sufficient strength after curing of 7, 14 or 28 days, the T is
suspended invertedly from the upper brick and weights are attached to the lower
brick
v Weights
are gradually increased till both bricks split from each other
Special Mortars
Light weight
Mortar
v Ordinary
cement or lime mortar including asbestos. Fibres, jute fibre, wood powder, saw
dust etc.
v For
developing adhesion under special conditions, small quantities of glue can be
added to mortars
v Potable
water should be used
v Used
for heat or soundproof structures
Fire
Resistant Mortar
v Obtained
by mixing firebricks or fire clays with aluminous cement
v Usual
proportion is one part aluminous cement and two parts powdered fire cay
v Withstand
the effects of very high temperature v Used for lining of furnaces, fire places and ovens etc.
X-Ray
Shielding Mortar
v Special
heavy mortars (2.7 gm/cm3) are used to cover walls and ceiling of
X-ray cabinets
Lean Mortar
v Cement/lime
mortar with very small proportion of cementing material
v Used
to fill the cracks, faults or narrow joints. The process is known as ‘Grouting’
CONCRETE
v Concrete
is an artificial material, obtained by mixing together cementing material,
coarse aggregate, fine aggregate and water
v If
cement is used as cementing material in the mix, it is known as plain cement
concrete
v If
steel rods are embedded in the plain concrete, it is then called reinforced
cement concrete, abbreviated as RCC.
v If
instead of cement, lime is used as cementing material in the mix, the resulting
mass is termed as lime concrete
Classification of Concrete
Concrete
Classification
Ø Mud Concrete
Ø Lime Concrete
Ø Cement Concrete
Mud Concrete
v This
concrete does not carry any importance
v It
is prepared by mixing brick bats in mud mortar
v Sometimes
crushed stone may be mixed with mud mortar to form mud concrete
v Mud
concrete is used for preparing hard base, over which lime concrete may be laid
and then permanent flooring may be spread
Lime
Concrete
v This
concrete carries lot of importance
v Hydraulic
lime is always used in this concrete
v Fine
sand or finely ground surkhi is used as fine aggregate and brick chips or
crushed stone is used as coarse aggregate
v Firstly,
lime and sand/surkhi are mixed together by adding suitable amount of water
resulting lime mortar
v Prepared
lime mortar is spread over coarse aggregate stacked in uniform layer and mixed
by manual labor
v It
is used
ü Extensively
in foundations of two or three storied buildings
ü In
preparation of hard base for floors
ü Over
roof slabs
Cement
Concrete
v Cement
concrete is very important structural material & there is no structural
element that cannot be made from cement concrete or RCC
v It
should be carefully designed, mixed, placed and cured
v Cement
concrete is prepared by mixing together cement, sand, crushed stone/brick chips
and water
v All
the ingredients of the cement concrete when freshly mixed, produce a plastic
mass which can be poured into suitable forms or moulds to give desired shape to
the resulting solid mass
v RCC
is used in all kinds of civil engineering structures
Ingredients of Cement Concrete
No. |
Ingredient |
Function of Ingredient |
1 |
Cement |
Impart binding properties & convert the plastic mix to
a solid mass |
2 |
Water |
• Chemical
reaction with cement • Provide
workability |
3 |
Coarse Aggregate
(Crushed Stone/Brick Chips) |
Provide mass or volume to
the concrete & reduce
shrinkage effects on it |
|
|
|
4 |
Fine Aggregate (Sand) |
|
Desirable Properties of Cement Concrete Ingredients
Water Cement Ratio (W/C Ratio)
v It
is the ratio of water to cement in a concrete mixture
v Strength
and workability of the concrete greatly depend on the amount of water
v For
a particular proportion of materials, there is a specific amount of water that
gives the optimum strength to the concrete
v Amount
of water more or less than the specified amount, causes decrease in the
strength of the concrete
Water
ü
Potable
or Drinking Water
ü
Free
from acids, alkalies & decayed vegetable matter
Coarse
Aggregate
ü angular shape & Rough surface
ü having smaller porosity & absorption capacity
ü free from deleterious materials (coal, mica, alkali etc.)
Fine
Aggregate
ü Properly Graded
ü free from salt & other impurities
Properties of Cement Concrete
ü
Properties
of Concrete in Plastic Range
ü
Properties
of Hardened Concrete
Properties
of Concrete in Plastic Range
Workability
v It
is a measure of ease with which concrete can be handled from the mixer stage to
its final fully compacted stage
v The
proportion and properties of water, cement and aggregates influence the
workability of concrete
Elements that Effects Workability
No. |
Element |
Corresponding Effect |
1 |
Quantity of water in the mix |
Increased amount of water
increases workability |
2 |
Proper
grading of aggregate mix |
If FA as well as CA are
properly graded, workability increases |
3 |
Amount of cement |
Increased amount of cement
increases workability |
4 |
Ratio of FA & CA |
If proportion of CA is
reduced in relation to FA, workability can be improved |
5 |
Particle shape |
Rounded size particles
increases workability |
6 |
Admixture |
Adding of admixture
increases workability |
7 |
Method of Compaction |
Stiff or less workable concrete can be used, if compacted
by vibrator |
Segregation
v Tendency
of separation of CA particles from the concrete mass is called segregation
v Harmful
for concrete strength
Causes of Segregation
v When
concrete mixture is lean and too wet
v When
larger and rough textured aggregate is used
Avoidance of Segregation
v Addition
of little air entraining agents in the mix
v Restricting
the amount of water to smallest possible amount
v All
the operations like handling, placing & compaction are carefully conducted v Concrete should not be allowed to
fall from larger heights
Bleeding
v The tendency of water to rise to the surface of freshly laid
concrete is known as bleeding
Problems due to Bleeding
v Delays
in finishing
v Loss
of particles of sand & cement
Causes of Bleeding
v Lack
of fines
v Too
much amount of water
Remedies of Bleeding
v By
adding more cement
v By
properly designing the mix and using minimum quantity of water
v By
using little air entraining agent
v By
increasing finer part of fine aggregate
Properties of Hardened Concrete
No. |
Properties |
1 |
Compressive Strength |
2 |
Tensile & Bond Strength |
3 |
Impermeability |
4 |
Resistance to wear, weather & chemical
attacks |
5 |
Shrinkage |
6 |
Creep |
7 |
Thermal Expansion |
8 |
Elasticity |
Factors Affecting Proportions of Concrete
W/C Ratio
v Strength,
elasticity, durability and impermeability of concrete is ncreased with decreas
in W/C ratio, provided the concrete is workable
v Shrinkage
increases with larger W/C ratio
Cement
Content
v With
increase in cement content, W/C ratio is decreased and consequently strength,
elasticity, durability and impermeability is increased
v More
cement, improved workability increase shrinkage
Temperature
v Rate
of setting and hardening of concrete is high at higher temperature
Age of
Concrete
v Strength
of concrete goes on increasing with age, though the rate of increase becomes
very slow as time passes
Aggregate
v Size,
shape & grading of aggregate control the concrete properties to a large
extent
v Larger
the size of the aggregate, greater will be the strength, provided mix is
workable
v Properly
graded aggregates give better workability and strength than poorly graded mixes
Curing
v Curing
is the process of keeping the setting concrete damp, so that complete hydration
of cement is brought
v Curing
improves strength, resistance to wear & weather
v It
reduces shrinkage
v It
increases impermeability and durability of concrete
Frost
v Causes
disintegration of concrete
Entrained
Air
v The
entrained air in concrete is due to incomplete compaction
v It
reduces the strength of concrete
v It
also increases permeability
Mixing of Concrete
v The
process of mixing cement, water, FA & CA in suitable proportion is known as
mixing of concrete
v This
process should ensure uniform color, consistency and homogeneity of the
concrete
v Segregation
should not take place during process of mixing
Hand Mixing
v Hand
mixing is used, where quantity of concrete is very small
v Firstly,
cement and sand are mixed dry on a clean, dry & hard platform
v Dry
mixing is continued until the mix attains uniform color
v The
mix is spread over the measured stock of coarse aggregate in required amount
and they are mixed dry again to have uniform color
v A
hollow is made in the middle of the mix and about 75 % of the required amount
of water is added
v Mixing
is done and remaining water is added to acquire uniform workability
Machine
Mixing
v On
large works, machine mixing proves economical and convenient
v Concrete
produced by machine mixing is more homogeneous and can be prepared with
comparatively lesser W/C ratio
v The
concrete mixers may be of two types
ü Batch
Mixers
ü Continuous
Mixers
v Batch
mixers mix and discharge each load of materials separately
v Continuous
mixers produce steady stream of concrete as long as it is in operation
v Batch
type mixers are mostly adopted
Transporting the Concrete
v Concrete
prepared, either by hand mixing or machine mixing has to be transported to its
place of use, before hydration of cement starts
v During
transportation, efforts should be made to prevent segregation or less of any of
the ingredients
v The
method of transportation of concrete depends on the quantity of concrete and
situation of work site
v Transportation
of concrete is done by
ü Pans
ü Wheel
barrows
ü Truck
mixers
ü Belt
conveyors
ü Pumps
Placing of Concrete
v The
concrete should be placed and compacted before its setting starts
Precautions
while Placing Concrete
v Concrete
should be laid continuously to avoid irregular and unsightly lines
v To
avoid sticking of concrete, form work should be oiled before concreting
v While
placing concrete, the position of form-work and reinforcement should not be
disturbed
v To
avoid segregation, concrete should not be dropped from height more than 1m
v Concrete
should not be placed in rains
v Walking
on freshly laid concrete should be avoided
Compaction of Concrete
v Consolidation
of plastic concrete is termed as compaction of concrete
v In
this process, efforts are only directed to reduce the voids in the concrete
v Compaction
of concrete can be done either manually or mechanically
Manual/Hand
Compaction
v It
is done with the help of steel tamping rods or timber screeds
v Narrow
& deep members are compacted with tamping rods
v Thin
slabs and floors are tamped with the help of screeds
Mechanical
Compaction
v It
is done with the help of vibrators
v Vibrators
produce vibrations, which, when transmitted to plastic concrete, make it flow
and affect compaction
Finishing of Concrete
v Finishing
means, giving desired smoothness to the surface of compacted concrete v Finishing can be done by
Screeding, floating or trowelling
Curing of Concrete
Curing is the operation by which moist conditions are
maintained on finished concrete surface, to promote continued hydration of
cement
Importance
of Curing
v If
proper curing is not done, complete hydration of cement will not take place and
concrete will not acquire its full intended strength
v Shrinkage
will develop in the concrete without proper curing
v
Curing also improves durability, permeability
and wear & weather resisting qualities
Methods of Curing
Shading Surface
ü To prevent evaporation of
water from the surface
ü To protect concrete surface
from heat, direct sun & wind
Covering
ü With hessian or gunny bags
Sprinkling Water
ü Water is sprinkled on the
surface from time to time
Ponding of Water
ü Water is filled in kiaries
formed on surface by sand or mud
ü Used for curing horizontal
surface
Membrane Curing
ü Concrete surface is covered
by water proof membrane that prevents
evaporation of water from concrete
ü Wax, bitumen emulsion,
plastic films etc. are common membrane materials
Steam Curing
ü Adopted in the case of
precast members
ü Hydration of cement is
brought within very short time
TIMBER
Ø Denotes
structural wood obtained from tree
Ø A
standing tree is called standing timber
Ø When
a tree has been cut and its stems and branches are roughly converted into
pieces of suitable lengths, it is known as rough timber
Ø When
a roughly converted timber is further sawn and converted into commercial size,
such as: plank, logs, batten, post, beam, etc., it is called converted timber
Difference
between wood and timber
Ø Wood
includes all types of wood which may be burning wood, structural wood,
furniture wood, etc.
Ø However,
wood used as a structural material is called timber
Advantages of using timber
Ø Easily
available everywhere
Ø High
salvage value
Ø Can
be transported easily by converting into small commercial sizes
Ø Working
with timber (i.e., repairing, alteration, addition, etc.) is easy
Ø Can
be easily jointed
Ø Not
corroded (so, it can be used in marine works)
Ø Light
weight
Ø Withstands
shocks better than iron and concrete
Ø Good
insulator of heat and electricity
Ø Good
sound absorbing material
Classification of trees
Exogenous
trees
Ø These
trees increase in bulk by the formation of successive annual rings radially on
the outside under the bark
Ø Every
year a new ring is added to the tree section
Ø Age
of tree can be determined from the number of annual rings
Ø Used
for engineering purposes
Two types
i) Evergreen trees or conifers
ü Having
pointed needle-like or scale-like leaves bearing cone-shaped fruits
ü Yield
softwood
ü Examples:
The Pines, Fur, Kail, Ceder, Chir, Deodar and Cypress Trees
ii) Deciduous trees
ü Having
flat broad leaves, which fall in autumn and new leaves appear in spring
ü Yield
hardwood
ü Examples:
Oak, Mehogany, Teak, Sal, Gorjon, Chambal, Telsu, Nageshwar, etc.
Endogenous
trees
Ø These
trees grow inward by depositing each fresh layer internally.
Ø Thus,
the older formations/layers of wood material are on the outside
Ø They
grow vertically in a fashion that the links (approx. annual growth) placed
end-to-end with knot connecting two adjacent links Ø Example: Bamboo, Palm, etc.
Hardwood/Softwood
Ø Characteristically,
broad-leaved trees yield hardwood while conifers (needleleafed trees) yield
softwood
Ø Hardwoods
are dense with having narrow and well-defined annual rings.
Softwoods are comparatively less dense, lighter in
color
Ø They
are not very strong but are soft with straight grains
Ø Softwoods
have more uniformity of structure than hardwoods
Timber Section
Ø Consists of pith, heartwood, sapwood, cambium layer, inner
bark, outer bark and medullar ray (Fig. 15.1, page no. 287, Aziz)
Pith
Central
part, dark colored, consists of cellular tissues and nourishes the plant in its
young age; in old age, the pith dries up and decays; Sap is transmitted by
fibers deposited round the pith.
Cambium
Layer
A thin layer of sap lying between sapwood and the
inner bark; it is full of sap which is yet to convert into sapwood; this is
very sensitive layer; if it is exposed by removing the bark, cell stopped transmitting
sap into the inner part and the tree dies.
Medullar Ray
These are thin radial fibers, extending from cambium
layer right up to pith. These rays help in holding together annual rings of
both heartwood and sapwood. They may be continuous but mostly they are
broken.
Heartwood
Dark colored portion of the tree surrounding the
pith. Almost dead portion of tree and does not take active part in its growth.
It provides strongest and durable timber for various engineering purposes.
Sapwood
Light colored wood lying between heartwood and
cambium layer. Light in weight and is of recent growth containing a lot of sap.
This is the active part of the wood and thus helps in growth in the tree.
Felling of Trees
Cutting of trees in order to get timber from them is
called felling of timber. The following facts should be carefully considered
while felling trees
Season of
Felling
Trees should be cut only when sap is not active, i.e.,
in mid-summer and mid-winter. In autumn and spring sap is in vigorous motion,
hence felling should be avoided. For hilly region, mid-summer and for plain
areas, mid-winter are proper seasons for felling trees.
Age of Trees
Trees should be felled only when it has just attained
maturity. Under-aged trees would yield more of sapwood, while over-aged trees
develop certain defects in heartwood.
Method of
Felling Trees
Felling should be entrusted to an experienced person.
Before felling, slope of the tree is assessed and cut is given to the stem on the side of the slope of the
tree, as near to the ground as possible. Then cut is made on the opposite side
of the slope to fell the tree.
If tree is to be felled against the direction of the
slope, ropes are tied to the tree and pulled to the direction of felling by
giving suitable cut to the stem.
Conversion of Timbers
The process by which timber is cut and sawn into
suitable marketable sizes is known as conversion of timber. After felling,
stems and branches of trees are cut into logs of suitable lengths. The logs are
then transported to the saw-mill and converted into marketable sections (i.e.,
planks, battens, beams, etc.).
Sawing of
Timbers
ü Ordinary
sawing or cross sawing
ü Radial
or Rift sawing
ü Tangential
or slash sawing
ü Quarter
sawing
ü Combination
sawing
Seasoning of Timbers
The process of removing surplus moisture (in excess
of equilibrium moisture content) from freshly converted timber is seasoning.
Advantage of
Seasoning
v Seasoned
timber is light
v Improves
strength properties
v Easy
to transport and handle
v Timber
less liable to be attacked by fungus and insects
v Reduces
the tendency to shrink and warp
v Can
easily be worked with
v A
seasoned timber maintains the shape of timber article unchanged
Methods of
Seasoning
v Natural
seasoning
v Artificial
seasoning
v Water
seasoning
Natural Seasoning
v After
felling, timbers are sawn into commercial sizes;
v They
are stacked under covered shed;
v Sufficient
space is left around each sawn piece for free air-circulation;
v Also
known as air seasoning; natural air
remains circulating around each piece of the stack and in due course of time, seasoning is
brought about.
Advantages
v No
skilled supervision is required;
v Simple
and cheap method of seasoning;
v Thick
section can be successfully seasoned.
Disadvantages
v Since
depends on natural air, no control can be exercised over it;
v Slow
method; depends on climatic conditions,
size and shape of the timber;
v Seasoning
non uniform and uneven;
v Requires
large space;
v Moisture
cannot be brought to the desired level;
v Seasoned
timber may have end split;
v Liable
to be attacked by fungus and insects.
Artificial
Seasoning
The drying of timber by exposure to high temperatures
in a closed chamber or by applying chemicals, steam and smoke is termed as
artificial seasoning.
Advantages
of Artificial Seasoning
v Rate
of drying can be regulated;
v No
chance of timber being attacked by fungus and insects;
v Takes
short time;
v Desired
moisture content can be attained during seasoning;
v Better
control of air, temperature and humidity;
v Seasoning
more uniform;
v No
end splits.
Methods of Artificial Seasoning
1) Smoking;
2) Boiling;
3) Steaming;
4) Kiln
seasoning;
5) Chemical
seasoning;
6) Electrical
seasoning;
Water Seasoning
Timbers and logs are immersed and allowed to remain
in water for a couple of days, then dried in natural air. In this process, the
sap is diluted and is partly removed.
Decay or Disease of Timber
Occurs due to fungal action; the fungi feeds on
softwood and converts it into powder; however, decay does not occur either due
to any chemical action or due to fermentation of sap.
The Main
Causes of Timber Decay are
v Alternate
dry and wet conditions;
v Defective
seasoning of timber;
v Presence
of fungi and insects such as marine borer, beetles, termite, etc.
v Lack
of ventilation;
v Dark
and damp condition;
Timber Rots
v It
is a sort of timber decay. During rot disintegration of timber takes place and
gases like H2S and CO2 are generated.
v Two types
ü Dry
rot
ü Wet
rot
Dry Rot
v Disintegration
of converted timber by the harmful effects of certain fungi, which feeds on
timber and converts it into dry powder.
v Factors
responsible are the same as those responsible for decay;
v If
some timbers are affected by dry rot, the best way is to cut the affected
portion;
v Dry
rot may be preserved by using well-seasoned timber free from sap, and the
timber should be adequately ventilated by fresh air;
v Detection:
by tapping or scratching at one end and placing the ear at the other end of
log.
Wet Rot
v It
is the decomposition of timber caused by moisture
v It
is caused if alternate dry and wet conditions prevail around the timber
v Not
caused by fungal attack
v When
unseasoned timbers are exposed to rain and wind, they are liable to be attacked
by wet rot
v In
wet rot, the timbers get converted into grayish brown powder
v Can
be prevented by using well-seasoned timber; also using tarred or painted
timbers exposing to rain or water
Preservation of Timber
v Preservation
indicates an increase in life by developing resistance to insect attack, fungal
infection and disease of timbers
v A
preservative acts like a disinfectant
v A
seasoned timber, since dried, is hygroscope and
to prevent re-absorption of moisture and to impart immunity, the tissues
of dry/seasoned wood have to be soaked with some type of a preservative
v Seasoning,
therefore, prepares a timber for preservative treatment by driving away
moisture and sap
Choice of
Preservative is governed by
v Their
toxicity and poisonous effects
v Permanency
in their effect in treated wood
v Should
not be injurious to wood tissues
v Cheaply
available and safe to handle v Should
allow a decorative treatment
v Should
not disfigure exposed surface of timber
v Non-inflammable
v Should
have a good covering quality
Methods of
Preservatives
Charring
v Crude
method; No special preservative is used
v Timber
kept wet for 0.5~1.0 hour and then burnt to a depth of 15-mm and cooled with
water
v A
coal layer is formed on the surface which performs preservative functions
v Layer
is not affected by fungi, moisture or white ant
v Used
at lower ends of posts of timber
Tarring
v Application
of a layer of hot tar on the surface
v Generally
applied to an embedded ends of posts
Painting
v Performs
both aesthetic and preservative purposes
Creosoting
v Creosotes
are obtained by the distillation of coal, petroleum or wood substances
v Three
types: Coal-tar creosote, water gas-tar and wood tar creosote
v Creosote
oil is applied under pressure on wood surface
v Used
on piles, poles and railway sleepers, etc.
Water-Soluble
Chemical Salts
v Used
some chemical salts which are not toxic in nature and are also soluble in water
v They
are odorless and can be painted on drying
v When
appearance is important in wood, this type is most suitable
v Wood
treated with water soluble salts requires to be re-dried
v The
effects of these chemicals are lost gradually and so wood requires be painting
or varnishing for surface treatment
v Cheaper
than creosote treatment
v Example:
Zinc chloride treatment; Creosote oil + NaF→ known as Wolman’s salt
Artificial
Wood
Veneer
v Thin
sheets of timber of superior quality
v Obtained
by rotating wooden logs of the timber against a sharp knife of rotary cutter
v Thickness
0.4 to 6.0 mm or even more
v After
removing from parent logs, they are
dried in kiln to remove moisture
v Used
for manufacturing of plywood
Plywood
v Made
from multiple veneers
v Veneers
are taken in odd numbers and are placed one above the other at right angles in
successive veneers
v All
veneers held together with the help of adhesives
v 3-ply,
5-ply, 7-ply, etc. are available; that is, veneers are used in odd numbers in a
plywood
Advantages of plywood
v Suffers
little expansion or shrinkage due to change in moisture content
v Light
and available in large sizes
v Available
in decorative designs
v Not
liable to split and cracks
v Easy
to work with
v Make
use of costly timber in most economical manner
Impreg Timber
v Sunmica,
formica, sungloss, etc.
v Veneers
are partly or fully covered with resin;
v For
this purpose, veneers are taken and immersed in resin. The resin fills in the
wood cells and a consolidated mass is developed. The mass is then cured at a
temperature of about 150 to 1600° C
Characteristics
of Impreg Timber
v Strong,
durable, good looking, weather resistant, electrically insulated and resists
acidic effects
Compreg Timber
v Same
as impreg timber; except, they are cured under pressure
v More
durable and stronger than impreg timber
Fiber-Board
v Manufactured
from wood or other vegetable fibers;
they are rigid boards of thickness varying from 6 mm to 25 mm; width 1.2m and
length 3.5 m;
v The
pieces of woods, cane or other vegetable fibers are heated in a hot water
boiler; Due to boiling, the fibers get separated;
v These
fibers are put in a vessel and steam is admitted in it under a pressure;
v The
steam pressure is then suddenly increased to 70 kg/cm2and this pressure is
maintained for a few seconds;
v The
steam pressure is suddenly dropped down;
in doing so, the natural adhesive contained in fibers is completely
separated;
v Fibers
are taken out of vessel and cleaned off all superfluous gums;
v They
are spread on wire screen in form of loose sheets and pressed; the resulting
material is called fiberboard;
v Depending
on their form and composition, they are classified as insulating boards, medium
hardboards, hardboards, super hardboards and laminated boards.
v They may be used for following purposes
ü For
the construction of walls panels and suspended ceilings
ü Construct
partitions
ü Form-works
ü As
insulating materials against heat and sound ü As tabletops and for flush doors.
SOIL
v The
term soil is defined as an unconsolidated material, composed of solid
particles, produced by the disintegration of rocks
v The
void space between the particles may contain air, water
v The
solid particles may contain organic matter
Classification of Soil
Based on Grain Size
Some Soil
Classification Systems
1) Unified
Soil Classification System (USCS)
2) American
Association of State Highways & Transportation Officials (AASHTO)
classification
3) United
States Department of Agriculture (USDA) classification
USCS
USCS |
Symbols |
G |
Gravel |
S |
Sand |
M |
Silt |
C |
Clay |
O |
Organic |
W |
Well graded |
P |
Poor graded |
L |
Low plasticity |
H |
High plasticity |
Importance of Soil in Civil Engineering
v Any
Civil Engineering Structure needs a stable foundation and all foundations
constructed ultimately derive their support from the underlying soil
v Soil
is used in
ü Construction
of embankments, dams
ü As
a stabilized sub-grade for roads, airports & runways
ü Manufacturing
of bricks, tiles, mortar etc.
v Soil
is, therefore, of great importance to engineers as a material of foundation and
also as a material of construction
Basic Properties of Soil
v Moisture
Content
v Specific
Gravity
v Unit
Weight/Density
v Void
Ratio
v Porosity
v Relative
Density
v Permeability
v Capillarity
v Shrinkage
& Expansion
v Compressibility
v Shearing
Resistance
Shearing Resistance
v Internal
Friction
v Cohesion
𝝉 = 𝒄 + 𝝈
𝒕𝒂𝒏𝝋
Where,
𝜏 = 𝑆ℎ𝑒𝑎𝑟𝑖𝑛𝑔
𝑟𝑒𝑠𝑖𝑠𝑡𝑎𝑛𝑐𝑒
𝑜𝑟 𝑠ℎ𝑒𝑎𝑟 𝑠𝑡𝑟𝑒𝑛𝑔𝑡ℎ
𝑜𝑓 𝑠𝑜𝑖𝑙
𝑐 = 𝐶𝑜ℎ𝑒𝑠𝑖𝑜𝑛
𝑜𝑓 𝑠𝑜𝑖𝑙
𝜎 = 𝑁𝑜𝑟𝑚𝑎𝑙
𝑠𝑡𝑟𝑒𝑠𝑠 (𝑓𝑜𝑟𝑐𝑒)
𝑜𝑛 𝑡ℎ𝑒 𝑠𝑜𝑖𝑙 𝑏𝑒𝑖𝑛𝑔
𝑐𝑜𝑛𝑠𝑖𝑑𝑒𝑟𝑒𝑑
𝜑 = 𝐴𝑛𝑔𝑙𝑒
𝑜𝑓 𝑖𝑛𝑡𝑒𝑟𝑛𝑎𝑙
𝑓𝑟𝑖𝑐𝑡𝑖𝑜𝑛
Phase Diagram
Soil is a three-phase material which consists of solid particles which make up the soil skeleton and voids which may be full of water if the soil is saturated, may be full of air if the soil is dry, or may be partially saturated as shown in Figure
Figure: Air,
Water and Solid phases in a typical soil
It is useful to consider each phase
individually as shown in following Table
Phase |
Volume |
Mass |
Weight |
Air |
VA |
0 |
0 |
Water |
VW |
MW |
WW |
Solid |
VS |
MS |
WS |
Index Properties/Consistency of Soil
v Liquid
Limit (LL)
v Plastic
Limit (PL)
Tests for Soil
Laboratory
Tsts
v Atterberg
Limit Test
v Grain
Size Analysis
v Direct
Shear Test
v Tri-axial
Test
v Consolidation
Test
Field Tests
v Standard
Penetration Test (SPT)
v Cone
Penetration Test (CPT)
v Vane
Shear Test
METALS
v Metals
are very much used for various engineering purposes v They are used in structures as doors, windows, pipes, roofing
etc.
Ferrous
Metals
ü Cast Iron
ü Wrought Iron
ü Steel
Non
Ferrous Metals
ü Aluminium
ü Copper
ü Lead
ü Zinc
ü Tin
ü Nobel Metals
• Gold
• Silver
• Platinum
•
Ferrous Metals
Iron
Ores
ü Haematite (Fe2O3)
ü Magnetite (Fe3O4)
ü Iron Pyrites (FeS2)
ü Limonite (2 Fe2O3. 3 H2O)
ü Siderite (FeCO3)
Pig Iron
v It
is the crude impure iron obtained from iron ores
v Pig
iron forms the basic material for the manufacture of cast iron, wrought iron
and steel
v Pig
Iron is weak and brittle material and cannot be used for structural purposes Composition
of Pig Iron
Element |
Percentage (%) |
Iron |
92-95 |
Carbon |
3-4 |
Impurities (Sulphur, Manganese, Phosphorous etc.) |
1-5 |
Cast Iron (CI)
Composition of Cast Iron
Element |
Percentage (%) |
Iron |
93-95 |
Carbon |
2-3 |
Impurities (Sulphur, Manganese,
Silicon, Phosphorous etc.) |
1-2 |
Properties
of Cast Iron
v Hard
and easily fusible
v Brittle
and cannot resist the effects of impacts and shocks
v Melting
temperature is 1250°C
v Does
not rust
v Becomes
soft when placed in water
v Cannot
be magnetized
v Can
be hardened by heating and sudden cooling
v Strong
in compression, but weak in tension
v Cannot
be riveted or welded
Uses of Cast
Iron
v For
making CI pipes
v For
man hole covers, flushing cisterns and other sanitary fittings
v As
compression members or struts in trusses
v For
all sorts of castings
Wrought Iron
Composition of Wrought Iron
Elements |
Percentage (%) |
Iron |
96 |
Carbon |
0.10 |
Impurities (Sulphur, Manganese,
Silicon, Phosphorous etc.) |
3.90 |
Properties
of Wrought Iron
v Ductile,
tough and malleable material
v Can
be easily forged and welded
v Cannot
be used for casting as it fuses with difficulty
v Corrosion
resistant
v Melting
temperature is about 1535°C
v Cannot
be hardened or tempered
v Purest
form of iron
Uses of
Wrought Iron
v Use
of it has been replaced to a very large extent by mild steel
v Used
where tough material is required
v Used
for rivets, railway couplings, water & steam pipes, bolts & nuts,
chains etc. v Used in
manufacturing hard steel
Steel
v Steel
is an intermediate form between cast iron and wrought iron
v Cast
iron contains the maximum amount of carbon, where wrought iron contains the
least
v Steel
is an alloy of iron and carbon
v Pure
iron without any carbon content is not very strong but when alloyed with
carbon, its strength can be increased remarkably
v Iron
when alloyed with carbon is known as steel, but when it is alloyed with other
non-ferrous metals, the resulting products are called steel alloys
Steel
Types
ü Low Carbon/Mild Steel
• Carbon upto 0.25%
ü Medium Carbon Steel
• Carbon 0.25 to 0.7%
ü High Carbon Steel
• Carbon 0.7 to 1.5%
Uses of Steel
Low Carbon/Mild Steel |
Welding, tubes, sheets, Rivet, screw, wire, structural shapes, Pipes,
shafts, bars etc. |
Medium Carbon Steel |
Axles, spring wire, Heavy duty machine parts
etc. |
High Carbon Steel |
Rails, hammers, wrenches, Cutting tool etc. |
Factors Affecting Physical Properties of Steel
v Strength,
elasticity, ductility etc. are the physical properties of steel
v The
properties get largely affected by
ü Carbon
content
ü Presence
of impurities like sulphur, phosphorous, silicon etc.
ü Heat-treatment
processes
Carbon Content
ü Higher the C content, more
is the hardness & strength
ü But consequent decrease in
ductility
Presence of Impurities
ü Excess S reduces ductility
& strength
ü Excess P decreases strength,
ductility & shock resistance
Heat Treatment
ü Increases hardness, resistance
to corrosion & heat
ü Render steel easily workable
Properties of Mild Steel
1) Specific
Gravity (SG) is 7.8
2) Melting
point is about 1400°C
3) Ductile
& malleable
4) Can
be easily welded and forged
5) Can
be given heat treatment easily
6) Can
be magnetized
7) Rusts
easily
8) Harder
& tougher than wrought iron
9) Used
for all types of structural works
Properties of Hard Steel
1) Can
be made permanent magnets
2) Can
be tempered and hardened easily
3) Can
be welded and forged easily
4) More
elastic and tough than mild steel
5) Readily
rusts
6) SG
is 7.9 and melting temperature about 1300°C
7) Tensile
and shear strengths are almost equal
Alloying Elements other than Carbon
Element |
Effect |
Boron |
Hardness |
Calcium |
Toughness, De-oxidant |
Lead |
High temperature strength,
Hardness |
Magnesium |
Strength, Resistance to
Corrosion |
Silicon |
Hardness |
Titanium |
Strength, Hardness,
Resistance to Corrosion |
Corrosion of Ferrous Metals
v Conversion
of metals into their oxides and other compounds by natural agencies is called
corrosion or rusting
Causes of
Corrosion
v Exposure
of the metallic surfaces to atmospheric agencies
v Exposure
to moist atmosphere
v Presence
of active gases in the surrounding atmosphere
v Presence
of harmful salts in the surrounding environment
Effects of
Corrosion
v Ferrous
metal (i.e., steel or iron) loses strength, hardness & ductility
Prevention
of Corrosion
Usual Methods of Preventing Corrosion are
v Tarring
v Electroplating
v Enameling
v Painting
v Galvanizing
v Metal
spraying
v Tin
plating
Market Forms of Steel
The available forms are
v Angles
v Channels
v T-Sections
v I-Sections
v Round
bars etc.
NON-FERROUS METALS
Aluminium
Aluminium
Ores
v Bauxite
(Al2O3. 2H2O)
Properties
v Pure
aluminium is a very soft & light metal
v Has
to be alloyed with other metals
v Highly
ductile & malleable
v Melting
point is 658°C
v SG
is 2.7
v Resists
corrosion very effectively
v Possesses
large toughness & tensile strength
v Silvery
white color
v Can
be rolled into sheets
v Good
conductor of heat and electricity
Uses
v When
alloyed with other metals is used for making pistons, cylinders in aero plane
engines
v Used
in electric cables
v Used
for making automobile bodies, utensils etc.
v Aluminium
paints are made from it
v Used
as protective coating to structural steel work
Copper
Copper Ores
v Copper
Pyrite (CuFeS2)
Properties
v Soft
and ductile
v Cannot
be rolled
v Color
is reddish brown
v Melting
temperature is 1083°C
v Specific
Gravity is 8.90
v Not
attacked by water at any temperature
v Good
conductor of electricity and heat
v Can
be alloyed with ither metals
v Can
be made strong, hard, tough and malleable by suitable treatment
v Highly
resistant to atmospheric corrosion
Uses
v Very
much used in electrical goods and cables, alloys, electroplating etc.
v Used
as material for damp-proof course
v Used
also in the manufacture of thin sheets, water pipes, taps, hardware fittings
etc.
Lead
Lead Ores
v Galena
(PbS)
Properties
v Soft
metal which can be cut by knife
v Melting
temperature is 326°C
v Specific
Gravity is 11.36
v Forms
black impressions on paper
v Lustrous
(shiny/glossy) metal having bluish gray color
v Not
affected by atmospheric corrosion
v Slightly
soluble in drinking water and may cause lead poisoning
v Resistant
to the action of alkalies, sulphuric acid and hydrochloric acid
v Malleable
(flexible/bendable) metal and can be rolled into thin sheets
Uses
v Compounds
of leads are commonly used as pigments for paints
v Used
in chemical processing industry
v Only
metal for making bullets
v Used
for storage cells, sanitary fittings, water proof and acid proof chambers v Used for gas pipes, printing
types etc.
Zinc
Zinc Ores
v Calamine
(ZnCO3)
v Zinc
Blend (ZnS)
Properties
v Specific
gravity is 6.86 v Not
affected by dry air
v Color
is bluish white
v Melting
temperature is 419°C
v Can
be rolled into sheets and drawn into wires between 100° to 150°C
v Brittle
at ordinary temperature
v Not
attacked by pure water
Uses
v Used
in electric cells and batteries
v Used
for galvanizing other metals
v Very
much used in pains and alloys
Tin
Tin Ores
v Cassterite/Tin
Stone (SnO2)
Properties
v When
a tin bar is bent, a peculiar sound occurs known as cry of tin
v Lustrous
& malleable metal
v Silvery
white color
v Melting
temperature is 232°C
v Specific
Gravity is 7.30
v Becomes
brittle when heated to a temperature of about 200°C
v Not
affected by dry air and pure water
Uses
v Used
in alloys with lead and other metals
v Used
in the form of protective & decorative coatings for metals like iron,
copper, brass, lead etc.
v Used
in form of foils for rapping cheese and other products
v Used
in the manufacture of collapsible tubes & pipes for toilet purposes
Nobel Metals and Their Uses
Metal |
|
Properties |
|
Uses |
Gold
(Au) |
|
Bright yellow metal SG is 19.3 Melting point is 1063°C Very malleable &
ductile metal Can be beaten to sheets as thin as 0.00001 mm Considered chemically least
active metal Does not oxidize when
exposed to year Maintains its brightness
for years |
|
For making coins &
jewellery Also used in electrical field |
Silver
(Ag) |
|
In malleability &
ductility, it is next to gold SG is 10.5 Good conductor of heat & electricity Cannot be oxidized by heat, but can be oxidized chemically & electrically |
|
Used very much in
producing photographic films & papers Used for coinage, jewellery Silver alloys are used for
providing heavy duty bearings Used for electroplating A special alloy of silver
called amalgam is most widely used by dentists as tooth filling material |
Platinum
(Pt) |
|
Grayish white color Very ductile &
malleable SG is 21.45 Melting point is 1773°C Not attacked by water, air,
sulphuric acid, hydrochloric acid & other acids Readily attacked by aqua
regia |
|
Used for making jewellery, scientific & surgical
instruments, standard weights and temperature measuring devices |
Some Important Alloys of Non-Ferrous Metals
Metal |
Alloy |
Composition |
|
Uses |
Aluminium (Al) |
Duralumin |
Al-94% Cu-4% Mg-0.5% Mn-0.5% Fe-0.5% Si-0.5% |
|
Air Craft industry Electric cable |
Copper (Cu) |
Bronze (Gun Metal) |
Cu-88% Sn-8~10% Zn-2~4% |
|
Making guns, bearings etc. |
v An
organic material with high molecular weight
v Prepared
out of resins, with or without the incorporation of fillers, plasticizers,
solvents or pigments
v Resins
are the basic raw materials in plastic industry, and generally there is no
shortage of the raw materials for the preparation of resins; it can be either
of natural origin or synthetic
v Synthetic
resins are produced by the methods of polymerization and condensation
Composition of Plastic
v Basically
an organic substance prepared from natural or synthetic resins
v Other
materials like fillers, plasticizers, hardeners, pigments may be added or
not
v Generally,
it is a compound of carbon with other elements such as oxygen, hydrogen,
nitrogen, etc.
v Carbon
combines with itself and other elements and forms more complicated compounds
Classification of Plastics
Basically, two types of plastics
i) Thermo-setting plastics ii) Thermo plastics
Thermo-Setting
Plastics
v This
variety requires great pressure and a momentarily heated condition during
shaping for subsequent hardening
v Heat
sets up cross-linkages between the molecules, the result of which is an
infusible mass that is very hard and resistant to heat
v It
is non-fusible and insoluble
v During
this process, chemical reactions take place, which are not reversible v The scrap of a thermo-setting
plastic article is not re-usable Thermo-Plastics
v This
variety hardens due to a physical change occurring in the materials
v They
could be softened by heat repeatedly, and the linkages between molecules are
rather loose
v Material
becomes more hard as it cools down
v The
process of softening by heat and hardening when cooled down could be repeated
indefinitely
v This
property allows the scrap from the broken and rejected articles, and the
trimmings from moulding machines to be re-used
v They
are required to be kept for sometimes in the mould until they cool down and
harden
v They
are soluble in many solvents
Various Materials for Plastics
Common
Thermo-setting Resins
i) Phenol formal-dehyde ii) Phenol
furfurol-dehyde iii) Urea formal-dehyde iv) Casein plastics (casein is an oirganic adhesive, reacts with
formal-dehyde to yield a plastic material)
Common
Thermo-plastic Resins
i) Cellulose derivatives:
Cellulose easter, Cellulose ethers ii) Acrylic resins iii) Vinyl resins iv) Styrene plastics (e.g.,
polystyrene)
Fabrication of Plastics
The various synthetics stated above do not possess
all the properties generally required in the finished plastic articles and have
only a limited range of application. For
the purpose of imparting desired properties and for their fabrication or
moulding and shaping, the moulding compounds are added.
Accordingly, the plastic falls into two categories
Simple
Plastics
v These
are composed of one polymer, as in the case of organic glass, which consists of
one synthetic resin such as methyl metacrylate
v They
are transparent and possess high optical properties
Complex Plastics
v These
contain one polymer and other compounds
v The
compounds are added to simple plastics to impart the products the required
properties
These components are
Fillers
v Added to moulding powder, to increase the bulk and lower the
cost; reduce shrinkage during moulding;
impart mouldability; also impart some desired properties to plastics. Examples:
cotton and wood fabric (fibrous fillers), wood powder (powdery fillers),
powdered quartz, glass, cloth and wooden veneers
(flaky or sheet like fillers)
Plasticizers
v Impart
plasticity or softness; they are non-volatile oily organic liquids; Examples:
tri-acetene, tri-butyl phosphate
Pigments
v Organic
dyes and imneral pigments are added to plastics to impart a desired color
Oiling Agents
v Oiling
agents such as stearine, graphite, parafin, wax, etc. to prevent plastics from
sticking to the mould
Hardeners
v Control
plasticity during moulding; also increase the hardness of resins
Foaming Agents
v To produce porous articles blowing agents such as sodium
bicarbonate, ammonium carbonate are used
Fabrication
Process of Plastics
It depends on the type of the
plastics (i.e., thermo or thermo-setting) and shape of the finished products
Blowing
v Thermo-plastic
is softened and then blown by air or steam into a closed mould.
Jars, toys, bottles are cast by this method
Casting
v Molten resin is poured in moulds and cured at about 700° C for
several days at low pressure; most suitable for cellular plastics
Calendering (Ironing)
v Plastic materials are made to pass through revolving
cylinders. While passing through first
three heated cylinders set, the plastic is turned into thin sheets; It is
cooled while passing through the 4th cylinder. Rollers may be
provided with artistic design to reflect them on the finished product. If cloth
is to be given plastic coating, it is inserted along with plastic material
between the second and third heated rollers
Laminating
v This process is adopted for thermo-setting plastics. Paper
sheets, asbestos, etc. are applied with plastic materials to form plastic
laminates. Having pleasing finished surface, used for ornamental and decorative
purposes
Moulding
v It is the most common method for the fabrication of plastic
articles. Various common processes are
ü Compression
moulding
ü Cold
moulding
ü Injection
moulding
ü Extrusion
moulding
ü Jet
moulding
ü Transfer
moulding
Properties of Plastics
General
Properties
v Possesses
a wide range of mechanical properties from soft, highly tensile and extensible
products to hard, rigid and brittle materials
v Properties
are usually associated with temperature; having higher coefficient of expansion
under heat
v Having
comparatively lower density than metals and hence they are light
v Having
low thermal conductivity
v Good
electrical insulators
Engineering Properties
v Compressive and tensile strength of
plastics is high, especially those of laminated plastics, moulded and impregnated
fibrous plastics
v Good workability, by virtue of which
plastics products can be manufactured to the required shape (e.g., toys,
bottles, sheets, yarns, woven cloths, etc.), by any of the processes, say,
casting, moulding, and extrusion
v Low wear and tear: Withstand wear and tear due to abrasion
satisfactorily
v Appearance and transparency
v Gluing of plastics products: The
surfaces of plastic products allow easy and strong gluing of lasting nature;
thus provides convenience in fabrication of plastic products
v Adhesiveness: Plastic glues and
adhesives are now becoming very common. They are not affected by fungi,
moisture and other climatic conditions; they form a very thin film of strong,
durable and covering capacity
v Chemical stability: Exhibit satisfactory
resistance to the corrosive and solvent actions of acids, alkalies and salt
solutions
v Water proofing quality: Plastics laminae
could be made waterproof, which can be used as padding for forming airtight and
gas-proof joints.
Use of Plastic in Building Construction
Flooring
v Versatile use; thermo plastics or polyvinyls are used for
floors in the form of tiles and sheets
Roofing
v Corrugated
sheets of phenolic-resin-bonded paper laminates manufactured in rather darker
shades; provides light, strong and corrosive resistant opaque roofing materials
Pipes
v PVC
pipes
Decorative Laminated Plastic Veneers
v Versatile sheets marketed under tradenames of formica,
sunmica, sungloss, decolum, etc.
Concrete Shuttering
v Moulds
and forms of FRP (fiberglass-reinforced-plastics) give the casting concrete
shapes of high quality
Doors and Window Frames
v Lightweight
flush doors and window frames are widely used from FRP
Internal Partitions and Wall Paneling
v FRP
used widely for this purpose
Temporary Shelters
v FRP
used
Water Storage Tanks
v FRP water storage tanks are found to be superior to steel and
concrete tanks; lightweight, durable, heat resistant, etc.
Furniture Item
v FRP chairs, benches and tables are being used for auditorium,
hotels, schools, theatre, etc.
Fiberglass Reinforced Plastic (FRP)
v Glass
fibers are used alone or in combination with cotton or jute fabric to prepare
fiberglass reinforced plastic products with synthetic resins like phenol
formaldehyde
v The
resins are dissolved in alcohol and the glass cloth/fiber is impregnated with
the resin solution. They are then subjected to heat and pressure
v The
panels thus produced are strong, durable and make excellent heat insulating
wall coverings
v Glass-fibers
and synthetic resins bonded together by a suitable synthetic adhesive and yield
glass-veneers like wood-veneers, which can be used in place woodveneers
v In
FRP, glass-fibers provide stiffness and strength, while resin provides a matrix
to transfer load to the fibers.
v Aesthetic
appearance, corrosion resistance, durability, dimensional stability, light
transmission, lightweight, etc. are the favorable properties for FRP, which
make it popular.
Good classification Thanks for sharing.
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